Quantitative Analysis of Organic Compounds

IMPORTANT

Quantitative Analysis of Organic Compounds: Overview

This topic covers concepts, such as, Quantitative Analysis of Organic Compounds, Estimation of Carbon and Hydrogen, Reactions for Estimation of Oxygen & Expression for Estimation of Oxygen etc.

Important Questions on Quantitative Analysis of Organic Compounds

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In Carius tube, an organic compound ' X ' is treated with sodium peroxide to form a mineral acid ' Y '. The solution of BaCl2 is added to ' Y ' to form a precipitate ' Z '. ' Z ' is used for the quantitative estimation of an extra element. ' X ' could be

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An organic compound on combustion gives 0.22 g of CO2, and 0.126 g of H2O. If the percentage of C in given organic compound is 40%, the percentage of hydrogen will be?

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A gas mixture has propane (C3H8) and butane (C4H10).  At S.T.P., 15.68 L of CO2(g) is produced when mixture is completely oxidised by excess of O2(g). If only propane is oxidised then CO2(g) produced consume 1 L of 0.6 M KOH for complete neutralisation. The mass% of C4H10 in mixture is (nearest integer)​

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During estimation of nitrogen present in an organic compound by Kjeldahl's method, the ammonia evolved from 0.73 g of the organic compound neutralised 100 mL of 0.5 N H2SO4. If 0.73 g of the organic compound is used in the Duma's method, then x mL of nitrogen N2 at 300K and 623 mm of Hg pressure. The value of x/30 is

(Aquesous tension at 300 K is 15 mm and R=0.08 atm Lmol K.

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The ammonia evolved from the treatment of 0.30 g of an organic compound for the estimation of nitrogen was passed in 100 mL of 0.1 M Sulphuric acid. The excess of acid required 20 mL of 0.5 M Sodium hydroxide solution for complete neutralization. The percentage of nitrogen in the organic compound is (Report the answer in the nearest integer).

MEDIUM
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0.25 gm of organic compound on analysis by Dumas method produce 32 ml of nitrogen gas at STP. The percentage of nitrogen is?

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The NH3 evolved from 0.5 gram of an organic compound in Kjeldahl method, neutralized 20 ml of M2H2SO4. Find the % of nitrogen :-

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Estimation of oxygen in an organic compound can be made by.

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Which of the following method is used for the estimation of oxygen?

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An organic compound weighing 0.244 g on combustion with dry oxygen produces 0.616 g of CO2 and 0.108 g of H2O. Determine the percentage composition of the oxygen in compound.

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During estimation of nitrogen present in an organic compound by Kjeldahl's method, the ammonia evolved from 0.5 g of the compound in Kjeldahl's estimation of nitrogen neutralized 10 mL of 1M H2SO4.​ The percentage of nitrogen in the compound is :

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In the Kjeldahl's method for estimation of nitrogen present in a soil sample, ammonia evolved from 0.75 g of sample neutralized 10 mL of 1M H2SO4. The percentage of nitrogen in the soil is

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Carbon and hydrogen are estimated in organic compounds by

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Carius method is used for the quantitative estimation of_____.

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In an estimation of S by Carius method 0.2175g of the compound gave 0.5825g of BaSO4​. Percentage of S is :

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During the estimation of phosphorous, 10 g of an organic compound gave 6.73 g of Mg2P2O7​. What is the percentage of phosphorous in the organic compound?

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In an organic compound, phosphorus is estimated as _____.